Reshiram

Reshiram is a dual-type Dragon/Fire legendary Pokémon, and serves as a villain in some of his appearances.

Pokemon White
Reshiram Serves as N's Legendary.

Pokemon White: The Movie
Sometime during the three years he spent traveling the world prior to the events of the film, Damon happened to overhear Reshiram calling to him while he observed the ruined Kingdom of the Vale alongside Mannes. Together, the two of them went down into the caves inside the Sword of the Vale, where they became separated. At the bottom of the cave Damon discovered the Dragon Stone containing Reshiram and reawakened it.

With Reshiram's help, Damon traveled to the villages of the People of the Vale and managed to convince them to support him. Its first appearance in the film comes when it helps Damon stop a giant tornado in the desert along with a herd of stampeding Bouffalant. It later appears in a flashback as Damon tells the story of his travels.

When he raises the Sword of the Vale and comes to be opposed by Ash, Cilan, Iris, Carlita and Juanita, Damon summons Reshiram to aid him. It battles Juanita's Golurk, which Reshiram easily defeats.

The second time it fights Golurk, it is interrupted by Zekrom, which Ash has discovered and allied with. The two dragons battle after Zekrom drops Ash at the castle, ending in Reshiram's defeat. Zekrom and Reshiram then realize that Damon's actions have unleashed a corrupted Dragon Force that threatens to destroy the world, and both dragons blows away the clouds to reveal this fact to Damon.

In the Pokémon RéBURST manga
Fraud, a leader of the villainous Great Gavel has a Reshiram in which he can use as a Burst form.