Deathstroke is a killing machine that is essentially master of every form of physical combat, ranged combat and of stealth. He is a superhuman that will use whatever methods takes to terminate a target.
That being said, Green Goblin is a much stronger superhuman, has a more advanced arsenal, can fly and is very cunning. Yes, he has a double personality but that has never hampered him in combat. Any character that is able to ragdoll Peter Parker on various consistent occasions is going to be a threat.
I think Goblin wins with very high difficulty.