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Demon King Psycho is the ruler of the Madou crime syndicate and the main antagonist of Space Sheriff Sharivan. He later returns as the main antagonist of the movie Kamen Rider x Super Sentai x Space Sheriff: Super Hero Taisen Z.

History

Space Sheriff Sharivan

Though Psycho was immobile at first, he eventually uses his fully mobile cyborg Psychorror as an extension of himself, armed with twin swords. When Sharivan and Gavan enter his fortress, they discover that he uses two bodies at once. Sharivan destroys his immobile self while Gavan simultaneously destroys his second body.

Kamen Rider × Super Sentai × Space Sheriff: Super Hero Taisen Z

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Demon King Psycho in Super Hero Taisen Z

At some point, Psycho was able to revive Strategist Reider, who set in motion a plan to revive Psycho at full power, assembling Space Shocker from revived past foes of the Kamen Riders to serve as a front for Madou's return and to capture Psycholon, who housed a fragment of Psycho's soul that could be used to absorb magic and bring back Psycho.

Eventually, after the Galactic Union Police fire the Super Dimensional Cannon at Earth in order to destroy Space Shocker, Reider uses his magic to hijack the energy of the beam to complete the Demon King's resurrection. The resultant explosion provides enough power for it, before Reider perishes, just to later return as Space Reider, bringing several other monsters to the fight.

Psycholon is also overcome by the energy surge and is put under Madou's control as well, fusing back into Demon King Psycho. Psycho and his army of revived monsters then attack the Kamen Riders, Super Sentai and Space Sheriffs and start to overwhelm them, but an army of Kamen Riders and Super Sentai led by Kamen Rider 1 and Akaranger arrives to reinforce their fellow superheroes against Madou. As Psycho wreaks havoc, Yoko calls out for Psycholon and it manages to break free from Psycho's control, Psycho fires an attack at her, only for Psycholon to block the attack, sacrificing itself to protect Yoko. After being weakened by Space Sheriffs Gavan Type G, Sharivan and Shaider, Demon King Psycho is ultimately defeated when the Kyorugers' Kyoryuzin and Kamen Rider Wizard's WizarDragon combine and use their united powers to destroy the Demon King.

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           Super Hero Taisen Villains

Shocker-Zangyack Alliance
Dai-Shocker
Leader: Narutaki/Doktor G
Commanders: Apollo Geist | General Shadow | General Jark | General Black | Shadow Moon | Doras | N-Daguva-Zeba | El of the Ground | Orphnoch King | Joker Undead | Nurikabe | Gryllus Worm | Bat Fangire | Alligator Imagin | Llumu Qhimil | Weather Dopant | Mezool
Kaijin: Scorpion Man | Ghoster | Isoginjaguar | KomaThunder | Tiger-Roid | Cyborg Soldier Level 2 | Go-Gadoru-Ba | Go-Baberu-Da | Me-Garima-Ba | Go-Jaaza-Gi | Pantheras Luteus | Stellio Dextera | Brobajell | GuldMirage | Armadillo Orphnoch | Rhinoceros Beetle Orphnoch | Shell Undead | Tortoise Undead | Kasha | Musca Worm | Gecko Imagin | Bat Imagin | Mole Imagin | Medusa Legendorga | Warthog Fangire | Taurus Ballista | Cockroach Dopant | Spider Dopant | Kuwagata Yummy | Uni-Armadillo Yummy
Footsoldiers: Shocker Combatmen | Destron Combatmen | Dogma Fighters

Dai-Zangyack
Leader: Rider Hunter Silva
Commanders: Black Cross King | Hades God Cyclops | Hades God Drake | Hades God Sleipnir | Hades God Dagon | Yaiba of Darkness | Gai | Rei | Sea Fist Demon Rageku | Sanyo | Suugu | Long | Miranda | Rairaiken | Yogoshimacritein | Pollution President Batcheed | Doukoku Chimatsuri | Dereputa of the Meteor | Mons Drake of the Planet | Brajira of the Messiah | Deratsueigar | Zatsurig | Warz Gill | Ackdos Gill
Monsters: Shikabanen | Zodomas | Buramudo | Nanonanoda | Bowser | Yokubarido | Stargull | Almadon | Uorlian | Daiyarl | Shieldon | Vannain | Namono-Gatari of the Ortaurus Headder | Bari-Boru-Dara of the Uniberus Headder | Rō-O-Zā-Ri of the Hydrapan Headder | Chinomanako | Nunchaku Banki
Footsoldiers: Gormin | Sugormin | Dogormin

Demon King Psycho's Army
Space Shocker
Leader: Shadow Moon
Commanders: Space Ikadevil | Space Spider Man
Kaijin: Scorpion Man | Saboteguron | Ghoster | Zanjioh | Jaguarman | Girizames | Schwarian | Zu-Zain-Da | Sonorabuma | Buzzstinger Wasp | Arch Orphnoch | Tortoise Undead | Gecko Imagin | Pearlshell Fangire (Blue) | Bat Fangire | Beetle Fangire | Bat Dopant | Beast Dopant | Pteranodon Yummy | Kamakiri Yummy | Ika-Jaguar Yummy | Musca Zodiarts | Scorpion Zodiarts | Sagittarius Zodiarts | Skydain | Groundain
Footsoldiers: Shocker Combatmen | Chaps

Space Crime Syndicate Madou
Leader: Demon King Psycho
Commanders: Space Reider

Army of Resurrected
Rhino Doubler | Lizard Doubler | Zan Vardo | Karateloid | Bulldozerloid | Parabolaloid 2 | Chief of Staff Damaras | Development Technical Officer Insarn | Dyrandoh | Stargull | Sneak Brothers | Dogormin | Doukoku Chimatsuri | Dayu Usukawa | Chinomanako | Nunchaku Banki | Long | Sanyo | Suugu | Sea Fist Demon Rageku | Furious Demon God Gai | Grand Beast Rei | Agent Abrella

Badan Empire
Leader: Generalissimo of Badan
Commanders: Ambassador Darkness | Kamen Rider Fifteen | Llumu Qhimil | General Shadow | High Priest Baraom | General Jark
Kaijin: Scorpion Man | Saboteguron | Ghoster | Zanjioh | Shiomaneking | Poison Lizard Man | Jaguarman | Girizames | Hiruchameleon | Ganikomol | Turtle Bazooka | Marshal Machine | Sword Master Birugenia | Schwarian | Doras | Garai | Suddendas | Bird Dopant | Kamakiri Yummy | Ika-Jaguar Yummy | Shocker Greeed | Chameleon Zodiarts | Libra Zodiarts | Arachne
Footsoldiers: Shocker Combatmen | Destron Combatmen | Combat-Roids | Chaps
Allies: General Schwarz

2015 Shocker
Leader: Great Leader of Shocker
Commanders: General Black | General Shadow | Marshal Machine | High Priest Darom | General Jark | Super Galaxy King | Schwarian | N-Gamio-Zeda | Lobster Orphnoch | Weather Dopant | Sagittarius Nova | Phoenix | Demushu | Roidmude 089 | Kamen Rider 3
Kaijin: Garagaranda | Cheetahkatsumeri | Zanjioh | Shiomaneking | Poison Lizard Man | Poison Lizard Man | Girizames | Turtle Bazooka | Roidmude 057 | Roidmude 016 | Roidmude 076
Footsoldiers: Shocker Combatmen

Game World
Eight Kirino | Another Hiiro | Kamen Rider Dark Kabuto | Kamen Rider Dark Drive | Kamen Rider Dark Ghost | Kamen Rider Genm Zombie Gamer

Shocker (Game World)
Leader: Shocker Leader III
Commanders: Ambassador Hell | Space Ikadevil | Redyue | Paradox Roidmude | Bat Amazon | Black Cross King | Raimein | Emperor Z | Gengetsu Kibaoni | Ginis
Footsoldiers: Shocker Combatmen | Buglars | Zorima | Moeba | Combatant Kuros

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