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Devlin Levin is the son of Kevin 11,000 who became best friends with Ben 10,000s son Ken Tennyson. When he met Kenny they hung out and liked to show off their abilities. Later on he is welcomed to the Tennyson's residence where he double crossed Ken captured him and freed his father from the Null Void. Kevin thanked him for freeing him but double crosses him and proceeds to kill Ken and Max until Ben comes to the rescue. Devlin was angered by Kevin's betrayal and decided to help defeat him. After Kevin was imprisoned he was worried they would imprison him to but instead they decided to bring him into their family and he accepted it.

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Main Villains
Vilgax | Aloysius Animo | Hex | Zs'Skayr | Highbreed | Aggregor | Maltruant | High Override

The Faction
Khyber | Malware | Dr. Psychobos | Khyber's Panuncian

Magic
Charmcaster | Michael Morningstar | Addwaitya

Forever Knights
Forever King | Driscoll | Enoch | Joseph Chadwick | Sir George | Sir Morton | Winston | Forever Ninja | Forever Knight

Highbreed
DNAliens | Mizaru | Simian

Negative 10
Rojo | Clancy | Sublimino

Flame Keepers' Circle
Dagon | Conduit Edwards | Esoterica

Circus Freaks
Zombozo | Acid Breath | Frightwig | Thumbskull | Zombie Clowns

Incursean Empire
Milleous | Attea | Raff

Bounty Hunters
Sixsix | Sevenseven | Eighteight | Synthroid | Sunder

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Dr. Viktor | Yenaldooshi | Mummy | Crujo | Lord Transyl | Corruptura

Vreedles
Octagon Vreedle | Rhomboid Vreedle | Isosceles Right Triangle Vreedle

The Hive
Elena Validus | Nanochips | Decoy Queen

Psyphon's Gang
Psyphon | Bug-Lite | Bubble Helmet | Liam | Gorvan | Sweet-Eels Sparklefunk | Tummyhead

Rooters
Proctor Servantis | Phil Billings | Swift

Vengers
Captain Nemesis | Kangaroo Kommando | Will Harangue

Future
Kevin 11,000 | Sploot | Subdora

Evil Bens
Albedo | Alien X | Bad Ben | Benzarro | Eon | Mad Ben | Nega Ben

Other Villains
Argit | Mr. Beck | Blue Leader | Camille's Ex-Boyfriend | Chronians | Collectimus | Great One | Heatbat | Hoodlum | Hulex | Jarett | Kolar | Captain Kork | Kundo | Lepidopterran Prisoner | Looma Red Wind | Mr. & Mrs. Mann | Morgg | Mutant Reptile Leader | Mutant Seagull | Nyancy Chan | P'andor | Poltroon | Prisoner 775 | Red Leader | Ragnarok | Seebik | Solid Plugg | Ssserpent | Sunny | Trumbipulor | Violet Offenders | Vulkanus | Vulpimancers | King Xarion

Robots
Slix Vigma | Computron | Stalker

Nemetrix Aliens
Buglizard | Crabdozer | Hypnotick | Mucilator | Omnivoracious | Slamworm | Terroranchula | Tyrannopede | Vicetopus

Antitrix Aliens
Bashmouth | Bootleg | Crystalfist | Dark Matter | Hot Shot | Quad Smack | Rush | Skunkmoth | Thornblade | Undertow | Wreakingbolt

Reboot
Kevin Levin | Charmcaster | Ectonurite Prisoner | Opticoid Prisoner | Loboan Prisoner | High Override | Maurice and Sydney | Mutant Alphas | Bug Gang (Queen Bee) | Tim Buktu | Lord Decibel | LaGrange | Steam Smythe | Weatherheads | Xerge | Xingo | Alien Chefs | Yawk | Nanny Nightmare | Boblins | Ground Hawg Gang | Fogg | Jack-A-Lope | Hydromander | Ice Screamer | Goblin | Space Slime

Redeemed
Kevin Levin | Devlin Levin | Zed | Blarney T. Hokestar | Skurd | Fistina

Crossover Villains
Alpha | Black Knight | V.V. Argost