I'll say no, since he didn't seem to want to shoot his maid and I think he mentioned having loved ones. Also, pretty much all of the MCU's Hydra agents are pretty much indoctrinated into Hydra's way of thinking from birth and cruelly trained to think that way, as revealed in Agents of SHIELD, so I think it would be very hard for any of those people, of whom Pierce very likely belongs, to qualify as PE. Besides, despite how despicable his plan is, it's clear that he does so out of a desire for order and peace, rather than a personal lust for power. Don't get me wrong, I think he's close, but not quite there.

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